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Chemicals can be a huge health and safety risk in any workplace, whether an operative is handling or near them. 

One of the hardest areas to protect your operatives adequately is hand protection.  You need to ensure complete safety and safeguarding whilst ensuring decent grip and manoeuvrability. 

There are 2 main standards you need to consider when sourcing your chemical protective gloves: 

EN ISO 374-1:2016

This standard provides gloves with one of 3 different classifications.  Type A, B or C.  The classification for each category is as follows: 

Category 

Minimum Breakthrough Time 

Number of Chemicals Tested 

Type A 

30 minutes 

6 

Type B 

30 minutes 

3 

Type C 

10 minutes 

1 

There is a list of 18 chemicals that can be used to achieve accreditation to EN ISO 374-1.  Each of them has a designated letter (or “code”) that identifies it in the glove’s rating: 

Code 

Chemical 

A 

Methanol 

B 

Acetone 

C 

Acetonitrile 

D 

Dichloromethane 

E 

Carbon Disulphide 

F 

Toluene 

G 

Diethylamine 

H 

Tetrahydrofuran 

I 

Ethyl acetate 

J 

n-Heptane 

K 

Sodium hydroxide 40% 

L 

Sulphuric Acid 96% 

M 

Nitric Acid 65% 

N 

Acetic Acid 99% 

O 

Ammonium hydroxide 25% 

P 

Hydrogen peroxide 30% 

S 

Hydrofluoric Acid 40% 

T 

Formaldehyde 37% 

 

EN 16523-1:2015

This standard looks at permeation.  Permeation is a step further than penetration (as tested by EN ISO 374-1), it’s defined as the movement of the chemical through the glove under continuous contact.  For a glove to be certified, 3 test samples must be taken from the palm, where a cuff is longer than 400mm a further 3 samples are taken from the wrist.  Samples must also be taken from any area where there is a seam.  Ratings are as follows: 

Performance Level 

Breakthrough Time (Permeation) 

1 

>10 minutes 

2 

>30 minutes 

3 

>60 minutes 

4 

>120 minutes 

5 

>240 minutes 

6 

>480 minutes 

You can see our full range of chemical protective gloves here. Alternatively, you can get in touch with us on 01443 741999 or sales@pksafetyuk.com